Synthesis of reduced graphene oxide–TiO2 nanoparticle composite systems and its application in hydrogen production Original Research Article International Journal of Hydrogen Energy, Volume 39, Issue 29, 2 October 2014, Pages 16282-16292 Pawan Kumar Dubey, Prashant Tripathi, R.S. Tiwari, A.S.K. Sinha, O.N. Srivastava
Graphical abstractReduced graphene oxide (rGO)–TiO2 nanoparticle composite system is prepared through the photocatalytic reduction of graphite oxide using TiO2 nanoparticles. Photoelectrochemical characterizations and hydrogen evolution measurements of these nanocomposites reveal that the presence of graphene sheets enhances the photocurrent density and hydrogen generation rate. In graphene–TiO2 nanocomposite, photogenerated electrons in TiO2 are scavenged by graphene sheets and percolate to counter electrode to reduce H+ to molecular hydrogen thus increasing the performance of water-splitting reaction.
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